Bis(chloroacetato)-κ2 O,O′;κO-methanol-κO-bis(2-methylfuro[3,2-c]pyridine-κN)copper(II)
نویسندگان
چکیده
In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxyl-ate O atoms of two chloro-acetate anions (monodentate and asymmetrically bidentate), two pyridine N atoms of 2-methyl-furo[3,2-c]pyridine and one methanol O atom. There is an intra-molecular O-H⋯O hydrogen bond. Inter-molecular C-H⋯O hydrogen bonds result in the formation of a three-dimensional network and π-π stacking inter-actions [3.44-3.83 Å] are observed between symmetry-related rings of 2-methyl-furo[3,2-c]pyridine. Further inter-actions in the crystal structure are a short Cl⋯Cl inter-action [3.384 (2)Å] and C-H⋯π inter-actions between 2-methyl-furo[3,2-c]pyridine rings.
منابع مشابه
A 2:1 cocrystal of the cis and trans isomers of bis[1,1,1,5,5,5-hexafluoropentane-2,4-dionato(1−)-κ2 O,O′]bis(4-phenylpyridine N-oxide-κO)copper(II)
The title compound is a co-crystal of the cis and trans isomers, namely cis-bis-[1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato(1-)-κ(2)O,O']bis-(4-phenyl-pyridine N-oxide-κO)copper(II)-trans-bis-[1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato(1-)-κ(2)O,O']bis(4-phenyl-pyridine N-oxide-κO)copper(II) (2/1), [Cu(C(5)HF(6)O(2))(2)(C(11)H(9)NO)(2)]. In both isomers, the coordination geometry of the Cu(2+...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008